个人简介
成江,男,汉族,1974年11月出生,浙江省义乌市人,中共党员,教授,博士生导师、硕士生导师。1995年获得南京大学应用化学学士学位,2001年获得南京大学高分子化学与物理专利硕士学位,2001年至2004年和上海有机化学所联培,于2004年获得南京大学有机化学博士学位。主持4项国家自然科学基金面上项目、一项国家自然科学基金青年基金项目。2012年为洪堡学者(experienced researcher)在德国亚琛工业大学开展工作。应用过渡金属催化的C-H键官能团化反应、自由基参与的有机合成方法学以及二氧化碳的化学固定反应等,发展一些具有药理、生理活性的先导杂环化合物骨架的快捷、绿色的构建方法。自2005年独立开展科研工作以来,共发表SCI论文140余篇,被引6000余次,H因子为45。其中Angew. Chem., Int. Ed., 1篇, Chem. Commun. 28篇,Org. Lett. 22篇(以上51篇均为Nature Index收录期刊),Adv. Synth. Catal. 10篇,以及J. Org. Chem. 23篇。
代表性论文
1. Rhodium-Catalyzed Reaction of Sulfoxonium Ylides and Anthranils toward Indoloindolones via a (4 + 1) Annulation. Wu, X.; Xiao, Y.; Sun, S.; Yu, J.-T.; Cheng, J.* Org. Lett. 2019, 21, 6653. (IF 6.579)
2. Visible-Light-Driven Palladium-Catalyzed Oxy-Alkylation of 2-(1-Arylvinyl)anilines by Unactivated Alkyl Bromides and CO2: Multicomponent Reactions toward 1,4-Dihydro-2H-3,1-benzoxazin-2-ones. Sun, S.; Zhou, C.; Yu, J.-T.; Cheng, J.* Org. Lett. 2019, 21, 6579. (IF 6.579)
3. The Reaction of o-Aminoacetophenone N-Tosylhydrazone and CO2 toward 1,4-Dihydro-2H-3,1-benzoxazin-2-ones. Xiong, H.; Wu, X.; Wang, H.; Sun, S.; Yu, J.-T. Cheng, J.* Adv. Synth. Catal. 2019, 361, 3538.(IF 5.646).
4. Rhodium-Catalyzed Reaction of Azobenzenes and Nitrosoarenes toward Phenazines. Xiao, Y.; Wu, X.; Wang, H.; Sun, S.; Yu, J.-T.; Cheng, J.* Org. Lett. 2019, 21, 2565. (IF 6.579).
5. Palladium/copper-catalyzed multicomponent reactions of propargylic amides, halohydrocarbons and CO2 toward functionalized oxazolidine-2,4-diones. Zhou C.; Dong Y.; Yu J.-T.; Sun S.*; Cheng, J.* Chem. Commun. 2019, DOI: 10.1039/c9cc07027c. (IF 6.319).
6. The Silver-Promoted Phosphonation/Alkynylation of Alkene Proceeding with Radical 1,2-Alkynyl Migration. Jin, S.; Sun, S.; Yu, J.-T.; Cheng, J.* J. Org. Chem. 2019, 84, 11177 (IF 4.785).
7. Rhodium-Catalyzed Relay Carbenoid Functionalization of Aromatic C-H Bonds toward Fused Heteroarenes, Wu, X.; Xiong, H .; Sun, S,; Cheng, J.* Org. Lett. 2018, 20, 1396. (IF 6.579)
8. Site-specific hydroxyalkylation of chromones via alcohol mediated Minisci-type radical conjugate addition, Chen, R.; Yu, J.-T.; Cheng, J.* Org. Biomol. Chem. 2018, 16, 1823. (IF 3.564)
9. Radical rearrangement of N-sulfonyl-N-aryl propynamides: proceeding with homolytic N-SO2 bond cleavage and 6-endo-dig cyclization toward 3-sulfonyl-2(1H)-quinolinones, Wang, B.; Jin, S.; Sun, S.; Cheng, J.* Org. Chem. Front. 2018, 5, 958 (IF 4.955).
10. Palladium-catalyzed CO-free cyclizative carbonylation of 2-benzylpyridines leading to pyridoisoquinolinones, Yang, R.; Yu, J.-T.; Sun, S.; Cheng, J.* Org. Chem. Front. 2018, 5, 962 (IF 4.955).
11. Rh-Catalyzed Annulation of ortho-C-H Bonds of 2-Arylimidazoles with 1,4,2-Dioxazol-5-ones toward 5-Arylimidazo[1,2-c]quinazolines, Wu, X.; Sun, S.; Xu, S.; Cheng, J.* Adv. Synth. Catal. 2018, 360, 1111 (IF 5.646).
12. Palladium-Catalyzed Safe Cyanation of Aryl Iodides with Hexamethylenetetramine, Yan, Y.; Sun, S.; Cheng, J.* J. Org. Chem. 2017, 82, 12888 (IF 4.785).
13. Palladium-Catalyzed [5+1] Annulation of 2-(1-Arylvinyl) Anilines and alpha-Diazocarbonyl Compounds toward Multi-functionalized Quinolines, Zhu, J.; Hu, W.; Sun, S.; Yu, J.-T.; Cheng, J.* Adv. Synth. Catal. 2017, 359, 3725 (IF 5.646)
14. The Base-Promoted Annulation of 2-Hydrazinyl Pyridine and CO2 toward Triazolones, Wu, X.; Sun, S.; Wang, B.; Cheng, J.* Adv. Synth. Catal. 2017, 359, 3855 (IF 5.646)
15. Copper-Catalyzed Arylsulfonylation and Cyclizative Carbonation of N-(Arylsulfonyl)acrylamides Involving Desulfonative Arrangement toward Sulfonated Oxindoles, Wang, H.; Sun, S.; Cheng, J.* Org. Lett. 2017, 19, 5844. (IF 6.579)
16. Copper-catalyzed radical 1,2-cyclization of indoles with arylsulfonyl hydrazides: access to 2-thiolated 3H-pyrrolo[1,2-a]indoles, Zhu, J.; Sun, S.; Xia, M.; Gu, N.; Cheng, J.* Org. Chem. Front. 2017, 4, 2153 (IF 4.955).
17. Palladium-Catalyzed Multicomponent Reactions of o-Alkynylanilines, Aryl Iodid.es, and CO2 toward 3,3-Diaryl 2,4-Quinolinediones, Wang, B.; Sun, S.; Yu, J.-T.; Jiang, Y.; Cheng, J.* Org. Lett. 2017, 19, 4319. (IF 6.579)
18. Synthesis of 2-Amino-3-hydroxy-3H-indoles via Palladium-Catalyzed One-Pot Reaction of Isonitriles, Oxygen, and N-Tosylhydrazones Derived from 2-Acylanilines, Chu, H.; Dai, Q.; Jiang, Y.; Cheng, J.* J. Org. Chem. 2017, 82, 8267. (IF 4.785)
19. 1,2-Arylalkylation of N-(arylsulfonyl)acrylamides using aliphatic aldehydes as the alkyl source, Yu, J.-T.; Chen, R.; Zhu, J.; Cheng, J.* Org. Biomol. Chem. 2017, 15, 5476. (IF 3.564)
20. Rh(III)-catalyzed bilateral cyclization of aldehydes with nitrosos toward unsymmetrical acridines proceeding with C-H functionalization enabled by transient directing group, Hu,W., Zheng, Q.; Sun, S.; Cheng, J.* Chem. Commun. 2017, 53, 6263 (IF 6.319).
21. The dearomative annulation between N-2-pyridylamidine and CO2 toward pyrido[1,2-a]-1,3,5-triazin-4-ones, Xia, M.; Hu, W.; Sun, S.; Yu, J.-T.; Cheng, J.* Org. Biomol. Chem. 2017, 15, 4064. (IF 3.564)
22. Aqueous MCRs of quaternary ammoniums, N-substituted formamides and sodium disulfide towards aryl thioamides, Zhou, Z.; Yu, J.-T.; Zhou, Y.; Jiang, Y.; Cheng, J.* Org. Chem. Front. 2017, 4, 413 (IF 4.955).
23. Carbon annulation of ortho-vinylanilines with dimethyl sulfoxide to access 4-aryl quinolines, Yuan J.; Yu J.-T.; Jiang Y.; Cheng, J.* Org. Biomol. Chem. 2017, 15, 1334 (IF 3.564).
24. Copper-mediated annulation of 2-(1-arylvinyl) anilines and aryl nitrosos towards 2,3-diaryl-2H-indazoles, Hu, W.; Yu, J.-T.; Liu, S.; Jiang, Y.; Cheng, J.* Org. Chem. Front. 2017, 4, 22 (IF 4.955).
25. Palladium-Catalyzed Arylcarboxylation of Propargylic Alcohols with CO2 and Aryl Halides: Access to Functionalized α-Alkylidene Cyclic Carbonates, Sun S.; Wang B.; Gu N.; Yu J.-T.; Cheng, J.* Org. Lett. 2017, 19, 1088 (IF 6.579).
26. The Construction of X-CN (X=N, S, O) Bonds, Yu, J.-T.; Teng, F.; Cheng, J.* Adv. Synth. Catal. 2017, 359, 26 (IF 6.5.646).
27. Multicomponent Coupling Reactions of Two N-Tosyl Hydrazones and Elemental Sulfur: Selective Denitrogenation Pathway toward Unsymmetric 2,5-Disubstituted 1,3,4-Thiadiazoles, Zhou Z.; Liu Y.; Chen J.; Yao E.; Cheng, J.* Org. Lett. 2016, 18, 5268 (IF 6.579).
28. Copper-catalyzed N-thioetherification of sulfoximines using disulfides, Zhu, H.; Yu, J.-T. * ; Cheng, J. * Chem. Commun. 2016, 52, 11098 (IF 6.319).
29. Iron-Mediated Annulation between Methylene Ketones and Diethan-olamines: a Sustainable and Scalable Procedure towards N-(2-Hydroxyethyl) Pyrroles, Hu, W.; Yu, J.-T.; Ye, D.; Zhou Z.; Sun, S.; Cheng, J.* J. Org. Chem. 2016, 81, 9389 (IF 4.849).
30. Rhodium-Catalyzed Annulation of Primary Benzylamine with α-Diazo Ketone toward Isoquinoline, Chu, H.; Xue, P.; Yu, J.-T.; Cheng, J.* J. Org. Chem. 2016, 81, 8009 (IF 4.849).
31. Formal [3+2] Reaction of α,α-Diaryl Allylic Alcohols with sec-Alcohols: Proceeding with Sequential Radical Addition/Migration toward 2,3-Dihydrofurans Bearing Quaternary Carbon Centers, Hu, W.; Sun, S.; Cheng, J.* J. Org. Chem. 2016, 81, 4399 (IF 4.849).
32. TBAI-Catalyzed Reaction between N-Tosylhydrazones and Sulfur: A Procedure toward 1,2,3-Thiadiazole, Chen, J.; Jiang, Y.; Yu, J.-T.; Cheng, J.* J. Org. Chem. 2016, 81, 271 (IF 4.849).
33. Palladium-catalyzed three-component reaction of N-tosyl hydrazones, isonitriles and amines leading to amidines, Dai, Q.; Jiang, Y.; Yu, J.-T.; Cheng, J.* Chem. Commun. 2015, 51, 16645 (IF 6.319).
34. The 3-Aza π-Allyl Palladium Derived from Imino Migratory in Palladium-Carbene: an MCRs Reaction Toward Multiple Substituted Indole Skeleton, Dai, Q.; Jiang, Y.; Guo, S.; Yu, J.-T.; Cheng, J.* Chem. Commun. 2015, 51, 14781 (IF 6.319).
35. Diethylene Glycol Serving as Ethyne Equivalent: A Sustainable Approach toward 2,3-Disubstituted Furan, Yu, J.-T.; Shi, B.; Peng, H.; Sun, S.; Chu, H.; Jiang, Y.; Cheng, J.* Org. Lett. 2015, 17, 3643 (IF 6.579).
36. Rh-catalyzed sequential oxidative C−H activation/annulation with geminal-substituted vinyl acetates to access isoquinolines, Chu, H.; Sun, S.; Yu, J.-T.;* Cheng, J.* Chem. Commun. 2015, 51, 13327 (IF 6.319).
37. Silver-Mediated N-Trifluoromethylation of Sulfoximines, Teng, F.; Cheng, J.;*Bolm, C.* Org. Lett. 2015, 17, 3166 (IF 6.579).
38. Copper(I)-catalyzed desulfinative carboxylation of sodium sulfinates using carbon dioxide, Sun, S.; Yu, J.-T.; Cheng, J.* Adv. Synth. Catal. 2015, 357, 2022 (IF 6.453).
39. Cs2CO3-Promoted Carboxylation of N-Tosylhydrazones with Carbon Dioxide towards α-Arylacrylic Acids, Sun, S.; Yu, J.-T.; Jiang, Y.; Cheng, J.* J. Org. Chem. 2015, 80, 2855 (IF 4.849).
40. Copper-catalyzed oxidative C(sp3)-H/N-H coupling of sulfoximines, amides with simple alkanes via radical process, Teng, F.; Sun, S.; Jiang, Y.; Yu, J.-T.;* Cheng, J.* Chem. Commun. 2015, 51, 5902 (IF 6.319).
41. Iodine-catalyzed ammoxidation of methyl arenes, Guo, S.; Wan, G.; Sun, S.; Jiang, Y.; Yu, J.-T.; Cheng, J.* Chem. Commun. 2015, 51, 5085 (IF 6.319).
42. Copper-Catalyzed N-Cyanation of Sulfoximines by AIBN, Teng, F.; Yu, J.-T.; Zhou, Z.; Chu, H.; Cheng, J.* J. Org.Chem. 2015, 80, 2822 (IF 4.849).
43. Di-tert-butyl Peroxide-Promoted α-Alkylation of α-Amino Carbonyl Compounds by Simple Alkanes, Peng, H.; Yu, J.-T.; Jiang, Y.; Yang, H.; Cheng, J.* J. Org. Chem. 2014, 79, 9847 (IF 4.849).
44. TBHP-promoted sequential radical silylation and aromatisation of aryl isonitriles with silanes, Wang, L.; Zhu, H.; Guo, G.; Cheng, J.* Yu, J.-T.* Chem. Commun. 2014, 50, 10864 (IF 6.319).
45. Copper-Catalyzed Cyanation of Disulfides by Azobisisobutyronitrile Leading to Thiocyanates, Teng, F.; Yu, J.-T.; Yang, H.; Jiang, Y.; Cheng, J.* Chem. Coummun. 2014, 50, 12139 (IF 6.319).
46. Di-tert Butyl Peroxide-Promoted Sequential Methylation and Intramolecular Aromatization of Isonitriles, Dai, Q.; Yu, J.-T.; Feng, X.; Jiang, Y.; Yang, H.; Cheng, J.* Adv. Synth. Catal., 2014, 356, 3341 (IF 5.646).
47. The Benzoyl Peroxide-Promoted Functionalization of Simple Alkane with 2-Aryl Phenyl Isonitrile, Sha, W.; Yu, J.-T.; Jiang, Y.; Yang, H.; Cheng, J.* Chem. Commun. 2014, 50, 9179 (IF 6.319).
48. The Copper-Mediated Oxidative N-Cyanation Reaction, Teng, F.; Yu, J.-T.; Y Jiang, Y.; Yang, H.; Cheng, J.*, Chem. Commun. 2014, 50, 8412 (IF 6.319).
49. The Benzoyl Peroxide Promoted Dual C-C Bond Formation via Dual C-H Bond Cleavage: α- Phenanthridinylation of Ether by Isocyanide, Wang, L.; Sha, W.; Dai, Q.; Feng, X.; Wu, W.; Peng, P.; Chen, B.; Cheng, J.* Org. Lett. 2014, 16, 2088 (IF 6.579).
50. The Bu4NI-catalyzed alfa-acyloxylation of ketones with benzylic alcohols, Guo, S.; Yu, J.-T.; Dai, Q.; Yang, H.; Cheng, J.* Chem. Commun. 2014, 50, 6240 (IF 6.319).
51. The carbomethylation of arylacrylamides leading to 3-ethyl-3-substituted indolin-2-one by cascade radical addition/cyclization, Dai, Q.; Yu, J.; Jiang, Y.; Guo, S.; Yang, H.; Cheng, J.* Chem. Commun. 2014, 50, 3865 (IF 6.319).
52. Copper-Mediated C3-Cyanation of Indole by the Combination of Amine and Ammonium, Liu, B.; Wang, J.; Zhang, B.; Sun, Y.; Wang, L.; Chen, J.; Cheng, J.* Chem. Commun. 2014, 50, 2315 (IF 6.319).
53. The Base-Promoted Formal Arylation of Benzo[d]oxazoles with Acyl Chloride, Wang, L.; Ren, X.; Yu, J.; Jiang, Y.; Cheng, J.* J. Org. Chem. 2013, 78, 12076 (IF 4.849).
54. Annulation of Alkynes with Aryl Ketal Hydrazones: Proceeding through C-H Activation and In Situ Directing Group Removal Leading to Indenones, Chen, S.; Yu, J.; Jiang, Y.; Chen, F.; Cheng, J.*, Org. Lett. 2013, 15, 4754 (IF 6.579).
55. Palladium-Catalyzed Cyanation of Aryl Halides with CuSCN, Zhang, G.; Yu, J.-T.; Hu, M.; Cheng, J.* J. Org. Chem. 2013, 78, 2710 (IF 4.849).
56. The Copper-Catalyzed C3-Formylation of Indole C-H Bonds Using Tertiary Amines and Molecular Oxygen, Chen, J.; Liu, B.; Liu, D.; Cheng, J.* Adv. Synth. Catal. 2012, 354, 2438 (IF 5.646).
57. The palladium-catalyzed desulfitative cyanation of arenesulfonyl chlorides and sodium sulfinates. Chen, J.; Sun, Y.; Liu, B.; Liu, D.; Cheng, J.* Chem. Commun., 2012, 48, 449 (IF 6.319).
58. Copper-Mediated Cyanation of Aryl Halide with the Combined Cyanide Source. Zhang, G.; Ren, X.; Chen, J.; Hu M.; and Cheng, J.* Org. Lett. 2011, 13, 5004 (IF 6.579).
59. Palladium-Catalyzed Desulfitative C-Arylation of Benzo[d]oxazole C-H Bond with Arenesulfonyl Chlorides. Zhang, M.; Zhang, S.; Cheng, J.* Chem. Commun. 2011, 47, 11522 (IF 6.319).
60. The palladium-catalyzed cyanation of indole C–H bonds with the combination of NH4HCO3 and DMSO as a safe cyanide source. Ren, X.; Chen, J.; Chen, F.;* Cheng, J.* Chem. Commun. 2011, 47, 6725 (IF 6.319).
61. Rhodium or Palladium-Catalyzed Cascade Aryl Addition/Intramolecular Lactonization of Phthalaldehyde with Potassium Organotrifluoroborates to Access 3-Arylphthalides. Luo, F.; Pan,S.; Pan,C.; Qian, P.; Cheng, J.* Adv. Synth. Catal. 2011, 353, 320 (IF 5.646).
62. Copper(I)-Mediated Cyanation of Boronic Acids. Zhang, G.; Zhang, L.; Hu, M.*; Cheng, J.* Adv. Synth. Catal. 2011, 353, 291 (IF 5.646).
63. Copper(II)-Catalyzed Ortho-Functionalization of 2-Arylpyridines with Acyl Chlorides. Wang, W.; Pan, C.; Chen, F.*; Cheng, J.* Chem. Commun. 2011, 47, 3978 (IF 6.319).
64. Copper-Mediated Methylthiolation of Aryl Halides with DMSO. Luo, F.; Pan,C.; Li, l.; Chen, F.*; Cheng, J.* Chem. Commun. 2011, 5304 (IF 6.319).
65. Rhodium-Catalyzed Cascade Reaction: Aryl Addition/Intramolecular Esterification to Access 3-Aryl and 3-Alkenyl Phthalides. Ye, Z.; Lv, G.; Wang, W.; Zhang, M.; Cheng, J.* Angew. Chem. Int. Ed. 2010, 49, 3607 (IF 11.709).
66. Cu(OTf)2-Mediated Chan-Lam Reaction of Carboxylic Acids to Access Phenolic Esters. Zhang, L.; Zhang G.; Zhang, M.; Cheng, J.* J. Org. Chem. 2010, 75, 7472 (IF 4.849).
67. Palladium-Catalyzed Cascade Aryl Addition/Intramolecular Esterification Reaction of Phthalaldehyde to Access 3-Aryl and Alkenyl Phthalides. Ye, Z.; Qian, P.; Lv, G.; Luo, F.; Cheng, J.* J. Org. Chem. 2010, 75, 6043 (IF 4.849).
68. Copper-Catalyzed Sequential Alkyl/Aryl or Vinyl Esterification of Dicarboxylic Acid Anhydrides with Trialkoxysilanes. Luo, F.; Pan, C.; Qian, P.; Cheng, J.* J. Org. Chem. 2010, 75, 5379 (IF 4.849).
69. Copper(II)-Catalyzed Ortho-Acyloxylation of the 2-Arylpyridines sp2 C−H Bonds with Anhydrides, Using O2 as Terminal Oxidant. Wang, W.; Luo, F.; Zhang, S.; Cheng, J.* J. Org. Chem. 2010, 75, 2415 (IF 4.849).
70. Copper-Catalyzed Thiolation of the Di- or Trimethoxybenzene Arene C-H Bond with Disulfides. Zhang, S.; Qian, P.; Zhang, M.; Hu, M.; Cheng, J.* J. Org. Chem. 2010, 75, 6732 (IF 4.849).
71. Palladium-Catalyzed Acylation of sp2 C-H bond: Direct Access to Ketones from Aldehydes. Jia, X.; Zhang, S.; Wang, W.; Luo, F.; Cheng, J.* Org. Lett. 2009, 11, 3120 (IF 6.579).
72. Rhodium-Catalyzed ortho-Benzoxylation of sp2 C-H Bond. Ye, Z. Wang, W.; Luo, F.; Zhang, S.; Cheng, J.* Org. Lett. 2009, 11, 3974 (IF 6.579).
73. Chelation-Assisted Palladium-Catalyzed Direct Cyanation of 2-Arylpyridine C-H Bonds. Jia, X.; Yang, D.; Zhang, S.; Cheng, J.* Org. Lett. 2009, 11, 4716 (IF 6.579).
74. Palladium-Catalyzed Aromatic Esterification of Aldehydes with Organoboronic Acids and Molecular Oxygen. Qin, C.; Wu,* H.; Chen, J.; Liu, M.; Cheng, J.;* Su, W.; Ding, J.; Org. Lett. 2008, 10, 1537 (IF 6.579).
75. The Palladium-Catalyzed Addition of Aryl- and Heteroarylboronic Acids to Aldehydes. Qin, C.; Wu, H.;* Cheng, J.;* Chen, J.; Liu, M.; Zhang, W.; Su, W.; Ding, J. J. Org. Chem. 2007, 72, 4102 (IF 4.849).
76. The Use of Calcium Carbide in One-pot Synthesis of Symmetric Diaryl Ethynes. Zhang, W.; Wu, H.; Liu, Z.; Zhong, P.; Zhang, L.; Huang, X.; Cheng, J.* Chem. Commun. 2006, 4826 (IF 6.319).
主要项目
共主持国家自然科学基金面上项目4项,青年基金项目1项。省基金杰出青年基金1项,省基金面上项目2项。
1. 国家自然科学基金面上项目:二氧化碳作为C1来源在合成杂环化合物中的应用(No. 21971025),2020.01-2023.12,直接经费65万元,在研
2. 国家自然科学基金面上项目:基于原位形成卡宾对烯基钯插入、迁移形的π烯丙基钯中间体的分子内环化反应研究(No. 21572025),2016.01-2019.12,直接经费65万元,在研;
3. 江苏省高校自然科学研究重大项目:简单烷烃的自由基官能团化研究(No. 15KJA150001),2014.07-2017.06,经费30万元,在研;
4. 江苏省自然科学基金面上项目:甲烷的官能团化研究(No. BK20171193), 2017.08-2019.07,经费10万元,在研;
5. 江苏省高层次创新创业人才引进计划,2013.01-2016.12,省助经费100万元,已结题;
6. 国家自然科学基金面上项目:过渡金属催化吸电子定位基团促进的苯环C-H 键官能团化(No. 22172028),2013.01-2016.12,经费80万元,已结题;
7. 国家自然科学基金面上项目:过渡金属催化卤代芳烃对芳醛的Barbier类型反应研究(No. 20972115),2009.01-2011.12,经费34万元,已结题;
8. 浙江省自然科学基金杰出青年科学基金项目:过渡金属催化C-H键对C-杂不饱和键的加成反应研究(No. R4110294),2011.03-2013.12,经费20万元,已结题;
9. 教育部科技重点项目:过渡金属催化通过C-H键活化的腈化以及膦化反应(No. 209054),2009.01-2010.12,经费10万元,已结题;
10. 国家自然科学基金青年项目:过渡金属催化共轭高聚物光电材料的合成、修饰以及表征(No. 20504023),2006.01-2008.12,经费26万元,已结题;
11. 浙江省自然科学基金面上项目 富电子大位阻有机膦配体的合成及在C-C、C-杂键形成中的应用(No. Y404039),2006.3-2006.10,经费5万元,已结题;
获奖项目
1. 常州市优秀科技论文三等奖,铜催化以偶氮二异丁腈为氰源过硫化物的氰化反应合成硫氰酸酯,第一完成人,2015年;
2. 浙江省科学进步奖三等奖,绿色化学技术及金属试剂在有机合成中的应用研究,第二完成人,2009年;
3. 浙江省教育厅高校科研成果奖一等奖,有机锆、有机膦等金属和元素有机化合物的合成与应用,第三完成人,2005年;
4. 温州市人民政府科技进步奖三等奖,有机锆、有机膦等金属和元素有机化合物的合成与应用,第三完成人,2005年。
所获人才项目及荣誉称号
1. 江苏省333高层次人才培养计划 第三层次,2016年;
2. 江苏省高层次创新创业人才引进计划 事业单位创新人才,2013年;
3. 江苏省高校“青蓝工程”中青年学术带头人,2012年;
4. 德国洪堡学者,资深研究员 2011年;
5. 浙江省自然科学基金杰出青年基金获得者 2010年;
6. 温州市科技特派员,2009年;
7. 浙江省高等院校中青年学科带头人,2007年;
8. 浙江省151人才第三层次,2006年;
9. 温州市551人才第二层次,2006年。
指导学生获奖情况
1. 2018年江苏省优秀硕士学位论文,过渡金属催化含氮杂环化合物合成反应研究
2. 江苏省优秀本科毕业论文三等奖,自由基环化菲啶硅烷合成反应研究,2016年;
3. 江苏省优秀本科毕业论文二等奖,基于单质硫的C-S键形成反应研究,2015年;
4. 浙江省第十一届“挑战杯”动感地带大学生课外学术科技作品竞赛二等奖,Rh/Cu/TBAF催化的芳基硅烷对炔烃的加成反应;
5. 浙江省研究生创新基金,过渡金属催化芳烃C—H键对碳杂不饱和键加成反应(Yk2008093);
6. 浙江省新苗计划,过渡金属催化通过C-H活化合成咔唑衍生物;
7. 浙江省大学生科技创新创业孵化项目,铜催化的苯硼酸的三氟甲基化(2010R424064);
8. 浙江省大学生科技科技成果推广项目,铜催化的芳基硼酸与羧酸生成芳酯的反应研究(2010R424058)。
9. 2010年度浙江省优秀硕士论文,铑催化的C-H键活化及钯催化的偶联反应研究
10. 2009年度浙江省优秀硕士论文,过渡金属催化钯、铜催化的偶联反应研究